benefi/srr-f1 - Fujifilm

SAFETY DATA SHEET 

Issue Date: 3 June 2013 Page 1 of 7 

Version No.: 01 (Supersedes Version: 00) 

Last Revision Date: 5 Apr 2010 

Product No.: 2361c 

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION 

1.1 Product Name BENEFI / SRR-F1 

1.2 Product Code: 872942 / 772942 

1.3 Recommended Use and Restriction on Use: Fixer for lithographic film. 

1.4 Manufacturer: FUJIFILM Asia Pacific Pte. Ltd. 

UEN: 199301558N 

1.5 Address: 15 Tuas Avenue 7 

Singapore 639270 

1.6 Business Phone Number: (65) 6862 2116 (Operating hours: 0830-1730 hours Mondays-Fridays) 

Fax: (65) 6861 4829 

Emergency Phone Number: (65) 6863 8753 

SECTION 2: HAZARDS IDENTIFICATION 

2.1 GHS Classification: 

Hazard Class Hazard Category Hazard Statement 

Skin corrosion/irritation: Category 2 Causes skin irritation. 

Serious eye 

damage/irritation: 

Category 2 Causes serious eye irritation. 

2.2 GHS label elements 

Pictograms: 

2.3 Signal Word: Warning 

2.4 Precautionary Statements: 

Prevention 

Wash your hands and face thoroughly after handling. 

Wear protective gloves/protective clothing/eye protection/face protection. 

Response 

IF ON SKIN: Wash with plenty of soap and water. 

If skin irritation occurs: Get medical advice/attention. 

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to 

do. Continue rinsing. 

If eye irritation persists: Get medical advice/attention. 

Take off contaminated clothing and wash before reuse. 

Storage 

None 

2.5 Disposal: 

See Section 13 of this Safety Data Sheet. 

Other Hazards Which Do Not Result in Classification 

Primary Hazards 

None 

Specific Hazards 

None 

(SDS-BENEFI - SRR-F1.doc, 06-Jun-2013)






SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 

3.1 Substance or Preparation: This product is a mixture. 

Chemical Name CAS No. % by Weight 

Water 7732-18-5 40 - 60 

Ammonium thiosulphate 7783-18-8 20 - 40 

Sodium acetate 127-09-3 3 - 7 

Sodium sulfite 7757-83-7 3 - 7 

Acetic acid 64-19-7 1 - 5 

Sodium thiosulphate 7772-98-7 1 - 5 

Aluminum sulphate 10043-01-3






SECTION 5: FIRE-FIGHTING MEASURES 

5.1 Suitable Fire-Extinguishing Media: 

Foam (alcohol-resistant foam), powder, and carbon dioxide are effective fire-extinguishing agents. 

5.2 Unsuitable Extinguishing Media: 

None under normal conditions. 

5.3 Hazardous Combustion Products: 

Ammonia, carbon oxides, sulfur oxides. 

5.4 Special Protective Actions for Fire Fighters: 

Cool the container(s) surface that is exposed to fire by spraying the surface with water. 

When fighting the fire, wear protective equipment (i.e., respiratory apparatus, chemical protection suit, 

gloves, boots, goggles, mask, etc.) as needed to avoid inhaling and/or skin contact with the chemical 

substance. Extinguish from the upwind direction. 

SECTION 6: ACCIDENTAL RELEASE MEASURES 

6.1 Personal Precautions, Protective Equipment, and Emergency Measures: 

Wear protective equipment (i.e., respiratory apparatus, chemical protection suit, gloves, boots, goggles, 

mask, etc.) as needed to avoid inhaling and/or skin contact with the chemical and/or vapours, if any. Work 

upwind, if possible. 

See Section 8 of this SDS for Personal Protective Equipment. 

6.2 Environmental Precautions: 

Do not allow to enter drains, sewers or water courses. 

The chemical substance in question should not be released into the environment (water, soil). 

6.3 Spill Containment and Cleaning Up: 

Minor Spills 

Avoid chemical contact by using personal protective equipment. 

Clean up spills immediately. 

Contain and absorb spill with sand, earth or other suitable absorbent material. 

Place spilled material in clean, dry, sealable, labelled container for disposal. 

Major Spills 

Clear area of personnel and move upwind. 

Call SCDF or local Fire Brigade. 

Wear full body protective clothing with breathing apparatus. 

Prevent, by any means available, spillage from entering drains or water course. 

Stop leak if safe to do so. 

Contain spill with sand, earth or other suitable absorbent material. 

Collect recoverable product into labelled containers for recycling. 

Neutralise/decontaminate residue. 

Collect solid residues and seal in labelled drums for disposal. 

Wash area and prevent runoff into drains. 

After clean up operations, decontaminate and launder all protective clothing and equipment before storing 

and re-using. 

If contamination of drains or waterways occurs, advise local Environmental Agency or Authority. 

SECTION 7: HANDLING AND STORAGE 

7.1 Precautions for Safe Handling: 

Limit all unnecessary personal contact. 

Wear protective clothing when risk of exposure occurs. 

Use in a well-ventilated area. 

Avoid contact with incompatible materials. 







When handling, DO NOT eat, drink or smoke. 

Keep containers securely sealed when not in use. 

Avoid physical damage to containers. 

Always wash hands with soap and water after handling. 

Work clothes should be laundered separately. 

Use good occupational work practice. 

Atmosphere should be regularly checked against established exposure standards to ensure safe working 

conditions are maintained. 

7.2 Conditions for Safe Storage: 

Store in original containers. 

Keep containers securely sealed. 

Store in a cool, dry, well-ventilated area. 

Keep out of reach of children. 

Store away from incompatible materials and foodstuff containers. 

Protect containers against physical damage and check regularly for leaks. 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 

8.1 Control Parameters/Occupational Exposure Limits: 

Ingredient CAS No. PEL/OEL Source 

Ammonium thiosulphate 7783-18-8 25 mg/m3 ACGIH TLV-TWA 

Ammonium thiosulphate 7783-18-8 35 mg/m3 ACGIH TLV-STEL 

Sodium acetate 127-09-3 Not established Not established 

Sodium sulfite 7757-83-7 Not established Not established 

Acetic acid 64-19-7 10 ppm ACGIH TLV 

Acetic acid 64-19-7 15 ppm ACGIH STEL 

Sodium thiosulphate 7772-98-7 Not established Not established 

Aluminum sulphate 10043-01-3 1 mg/m3 ACGIH TLV 

8.2 Appropriate Engineering Controls: 

Local exhaust ventilation usually required. If risk of overexposure exists, wear approved respirator. 

8.3 Personal Protective Equipment: 

Use the following protective equipment as needed: 

Respiratory Protection: Self contained breathing apparatus. 

Eye Protection: Wear approved safety goggles. 

Hand Protection: Wear protective gloves. Nitrile gloves are recommended, but be aware that the liquid 

may penetrate the gloves. Frequent change is advisable. Suitable gloves can be recommended by the 

glove supplier. 

Skin Protection: Apron and long sleeves are recommended. Wear suitable protective clothing. 

Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling 

the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective 

equipment to remove contaminants. 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 

9.1 Appearance Physical State: Clear liquid 

9.2 Colour: Slight yellow 

9.3 Odour: Acetic 

9.4 Odour Threshold: Not applicable 

9.5 Property Value Notes 

Melting Point 0 C 

Boiling Point 100 C 

Flash Point Not applicable (Not flammable) Closed cup 

Explosive Limit Not applicable Lower limit 

Explosive Limit Not applicable Upper limit 

Vapour Pressure Not applicable mmHg @ 20 C 







Vapour Density Not applicable Air=1 

Relative Density 1.284 25 C 

Solubility in Water Completely soluble Water at 20 C 

Solubility (Other) Not applicable 

Partition Coefficient: n-octanol/water Not applicable 

Viscosity Not applicable (like water) 

pH 4.85 25 C 

Evaporation Rate Not applicable Butyl Acetate = 1 

Flammability (Solid, Gas) Not applicable 

Auto-Ignition Temperature Not applicable (Not flammable) 

Decomposition Temperature Unknown 

SECTION 10: STABILITY AND REACTIVITY 

10.1 Reactivity/Incompatible Materials: 

Strong alkali, strong oxidizing agents. 

10.2 Chemical Stability: 

Stable under normal temperature and pressure. 

10.3 Possibility of Hazardous Reaction: 

Hazardous polymerisation will not occur. 

10.4 Conditions to Avoid: 

Excessive heat, contact with incompatible materials. 

10.5 Hazardous Decomposition Products: 

Nitrogen oxides, sulfur oxides. 

SECTION 11: TOXICOLOGICAL INFORMATION 

11.1 Acute Toxicity on Product Mixture: 

Oral LD50 Rat >5000 mg/kg 

Dermal LD50 ---- No data available. 

Inhalation LC50 ---- No data available. 

11.2 Acute Toxicity on Ingredients: 

Chemical Name CAS No. Acute Oral 

(LD50 mg/kg) 

Test Animal 

Ammonium thiosulphate 7783-18-8 2890 Rat 

Sodium acetate 127-09-3 3530 Rat 

Sodium sulfite 7757-83-7 820 Rat 

Acetic acid 64-19-7 3310 Rat 

Sodium thiosulphate 7772-98-7 Not established Not established 

Aluminum sulphate 10043-01-3 1930 Rat 

11.3 Skin Corrosion/Irritation: 

Causes skin irritation. 

11.4 Serious Eye Damage/Irritation: 

Causes serious eye irritation. 

11.5 Respiratory Organ or Skin Sensitisation: 

None. 

11.6 Germ Cell Mutagenicity: 

None. 







11.7 Carcinogenicity: 

None. 

11.8 Reproductive Toxicity: 

None. 

11.9 Specific Target Organ Toxicity: 

None. 

11.10 Aspiration Hazard 

Not applicable. 

SECTION 12: ECOLOGICAL INFORMATION 

12.1 Ecotoxicity of Product Mixture: 

No data available. 

12.2 Ecotoxicity on Ingredients: 

Chemical Name CAS No. Fish Toxicity Marine Organism 

Ammonium thiosulphate 7783-18-8 Not established Not established 

Sodium acetate 127-09-3 LC50(24h): 400 mg/l Baccinum undatum 

Sodium sulfite 7757-83-7 LC50(24h): 26400 mg/l Gambusia affinis 

Acetic acid 64-19-7 LC50(48h): 410 mg/l Leuciscus idus melanotus 

Sodium thiosulphate 7772-98-7 LC50(24h): 26400 mg/l Gambusia affinis 

Aluminum sulphate 10043-01-3 LC50(24h): 4-4.4 mg/L Salvelinus fontinalis 

12.3 Persistence and Degradability: 

No data on possible environmental effects have been found. 

12.4 Bioaccumulative Potential: 

No data available on bioaccumulation. 

12.5 Mobility: 

The product is water soluble and may spread in water systems. 

SECTION 13: DISPOSAL CONSIDERATIONS 

13.1 Disposal Method in Singapore: 

Dispose off in accordance to the Environmental Public Health (Toxic Industrial Waste) Regulations under 

the Environmental Protection and Management Act (EPMA). 

13.2 Disposal Method Overseas: 

Dispose off in accordance with all applicable local or national regulations. 

SECTION 14: TRANSPORT INFORMATION 

14.1 Land (ADR): 

UN Number: Not applicable. 

Class: Not classified as dangerous material. 

Packing Group: Not regulated. 

Proper Shipping Name: Not regulated. 

Subsidiary Risk: Not regulated. 

14.2 Sea (IMDG): 












Marine Pollutant (Yes/No): Not regulated. 

Packing Instructions: Not regulated. 

EmS (Emergency Schedule): Not regulated. 

Limited Quantity: Not applicable. 

Further Information: Material not classified for transport at sea. 

14.3 Sea (Annex II of MARPOL 73/78 and the IBC Code): 

Pollution Category: Not applicable. 

Ship Type: Not applicable. 

Product Name: Not applicable. 

14.4 Air (IATA): 






Label(s): Not regulated. 

Passenger and Cargo Aircraft: Packing Instruction None max. None 

Cargo Aircraft Only: Packing Instruction None max. None 

Limited Quantity: Not applicable. 

Further Information: Material not classified for air transport. 

14.5 Special Precautions: 

Not applicable. 

SECTION 15: REGULATORY INFORMATION 

15.1 Applicable Singapore Regulations: 

Workplace Safety and Health Act & Workplace Safety and Health (General Provisions) Regulations: 

This product is subject to the SDS, labelling, PEL and other requirements in the act/regulation. 

Environmental Protection and Management Act & Environmental Protection and Management (Hazardous 

Substances) Regulations: 

This product is subject to the requirements in the act/regulation. 

SECTION 16: OTHER INFORMATION 

16.1 Issued By: 

FUJIFILM Asia Pacific Pte. Ltd. 

This SDS is prepared in accordance with Singapore Standard SS 586 : Part 3 : 2008. 

16.2 Warranty: 

The above information is believed to be correct but does not purport to be all inclusive and shall be used 

only as a guide. The information in this document is based on the present state of our knowledge and is 

applicable to the product with regard to appropriate safety precautions.

benefi/srr-f1 - Fujifilm

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